CobaltMaghrebV1, Main, Exploration, bibRecord, 000208

Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate

Identifieur interne : 000208 ( Main/Exploration ); précédent : 000207; suivant : 000209

Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate

Auteurs : Thameur Sahbani [Tunisie] ; Wajda Smirani Sta [Tunisie] ; Mohamed Rzaigui [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3884988

Abstract

In the centrosymmetric title compound, [Co(C₄H₁₁N₂)₂(H₂O)₄](SO₄)₂·2H₂O, the Co^II atom is coordinated in a distorted octahedral geometry by four water O atoms and two piperazinium N atoms. These four water O atoms define an equatorial plane with a maximum deviation of 0.0384 (1) Å while the two piperazinium N atoms complete the octahedron in the axial positions. Neighboring complex molecules and sulfate anions are connected through an extensive network of N—H⋯O and O—H⋯O hydrogen bonds, which link the different chemical species into layers in the ab plane. Additional O_water—H⋯O hydrogen bonds involving the non-coordinating water molecules and C—H⋯O interactions connect these layers into a three-dimensional supramolecular structure.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884988

DOI: 10.1107/S1600536813030365
PubMed: 24454163
PubMed Central: 3884988

Affiliations:

Tunisie

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Serveur d'exploration sur le cobalt au Maghreb

Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate

Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate

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Abstract

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Serveur d'exploration sur le cobalt au Maghreb

Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate

Tetra­aqua­bis­(piperazin-1-ium)cobalt(II) bis­(sulfate) dihydrate

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Abstract

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Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate

Tetraaquabis(piperazin-1-ium)cobalt(II) bis(sulfate) dihydrate